Molecular parameters of post impact cooling in the Boltysh impact structure

Impact events have the potential to generate a number of long-term sources of heat that can lead to the initiation of hydrothermal systems when the impact occurs on a water- or ice-rich target. Such hydrothermal systems have been postulated as promising locations to search for evidence of past biological processes on Mars due to the prevalence of impact cratering as a surface process in Mars’s early history. In this study, we have used molecular parameters of the thermal maturity of organic matter combined with palynology and carbon isotope stratigraphy to study the post impact thermal history of crater fill sediments from the Boltysh crater, Ukraine

The Tagish Lake chondrite and the interstellar parent body hypothesis

Investigation of the solvent extractable organic compounds in Tagish Lake. The results are used to test the interstellar parent body hypthesis for the origin of extraterrestrial organic matter

A Raman spectroscopic study of carbon phases in impact melt rocks and breccias from the Gardnos impact structure, Norway

Raman spectroscopy suggests that the C was emplaced in at least two separate episodes into the impactites of the Gardnos impact structure

Organic indicators of alteration in the CR chondrites

A study of the organic components in the CR chondrite macromolecule in order to assess the role of pre-terrestrial alteration on the organic inventory

Analysis of Tagish Lake macromolecular organic material

Macromolecular material is, by far, the major organic component of meteorites. Flash pyrolysis GCMS has been used to investigate this organic component in Tagish Lake. It is more condensed, less susbtituted than Murchson

Dual isotopic composition of methane in Murchison meteorite

Dual isotopic composition (H and C) of methane extracted from a small sample of Murchison meteorite reveals a deuterium enrichment for this molecule, indicating the presence of interstellar hydrogen

Macromolecular organic acids in the Murchison meteorite

This study has detected bound organic acids within the Murchison meteorite organic macromolecule. Benzoic acid was the most abundant compound; other abundant compounds include C1 and C2 benzoic acids. Their origin and significance will be discussed

Hydrogen isotopic composition of the Tagish Lake meteorite: comparison with other carbonaceous chondrites

A study into the hydrogen isotopic characteristics of whole rock samples of carbonaceous chondrites and their comparison with a whole rock sample of the Tagish Lake meteorite

Nonlinear model evaluation: ι\iota shadowing, probabilistic prediction and weather forecasting

Physical processes are often modelled using nonlinear dynamical systems. If such models are relevant then they should be capable of demonstrating behaviour observed in the physical process. In this thesis a new measure of model optimality is introduced: the distribution of $\iota$ shadowing times defines the durations over which there exists a model trajectory consistent with the observations. By recognising the uncertainty present in every observation, including the initial condition, $\iota$ shadowing distinguishes model sensitivity from model error; a perfect model will always be accepted as optimal. The traditional root mean square measure may confuse sensitivity and error, and rank an imperfect model over a perfect one. In a perfect model scenario a good variational assimilation technique will yield an $\iota$ shadowing trajectory but this is not the case given an imperfect model; the inability of the model to $\iota$ shadow provides information on model error, facilitating the definition of an alternative assimilation technique and enabling model improvement. While the $\iota$ shadowing time of a model defines a limit of predictability, it does not validate the model as a predictor. Ensemble forecasting provides the preferred approach for evaluating the uncertainty in predictions, yet questions remain as to how best to construct ensembles. The formation of ensembles is contrasted in perfect and imperfect model scenarios in systems ranging from the analytically tractable to the Earth's atmosphere, thereby addressing the question of whether the apparent simplicity often observed in very high-dimensional weather models fails `even in or only in' low-dimensional chaotic systems. Simple tests of the consistency between constrained ensembles and their methods of formulation are proposed and illustrated. Specifically, the commonly held belief that initial uncertainties in the state of the atmosphere of realistic amplitude behave linearly for two days is tested in operational numerical weather prediction models and found wanting: nonlinear effects are often important on time scales of 24 hours. Through the kind consideration of the European Centre for Medium-range Weather Forecasting, the modifications suggested by this are tested in an operational model